Acrylate formation from CO2 and ethylene: catalysis with palladium and mechanistic insight.
نویسندگان
چکیده
We report the first catalyst based on palladium for the reaction of CO2, alkene and a base to form sodium acrylate and derivatives. A mechanism similar to a previously reported Ni(0)-catalyst is proposed based on stoichiometric in situ NMR experiments, isolated intermediates and a parent palladalactone. Our palladium catalyst was applied to the coupling of CO2 with conjugated alkenes.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 51 54 شماره
صفحات -
تاریخ انتشار 2015